Acetylene weak bands at 2.5μm from intracavity Cr2+:ZnSe laser absorption observed with time-resolved Fourier transform spectroscopy
نویسندگان
چکیده
منابع مشابه
Intracavity Laser Absorption Spectroscopy
continued on page 4 continued on page 4 Theodor Hänsch makes a time measurement. Introduction Absorption spectroscopy is one of the oldest scientific methods for studying atomic and molecular structure. It is also one of the most powerful research tools for providing information about the world around us. One important application is ultrasensitive trace gas analysis, which is used in many area...
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A femtosecond mode-locked laser is used for what is believed to be the first time as a broadband infrared source for high-resolution Fourier transform absorption spectroscopy. A demonstration is made with a Cr(4+):YAG laser. The entire nu(1)+nu(3) vibration-rotation band region of acetylene, observed after passing through a single-pass 80-cm-long cell, is simultaneously recorded between 1480 an...
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ClSO was produced as an intermediate upon irradiating a flowing mixture of Cl2SO and Ar with a KrF excimer laser at 248 nm. A step-scan Fourier-transform infrared spectrometer coupled with a small multipass absorption cell was employed to detect time-resolved absorption spectrum of ClSO. A transient spectrum in the region 1120-1200 cm(-1), which diminished on prolonged reaction, is assigned to ...
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A step-scan Fourier-transform spectrometer coupled with a multipass absorption cell was employed to detect temporally resolved infrared absorption spectra of CH(3)OSO produced upon irradiation of a flowing gaseous mixture of CH(3)OS(O)Cl in N(2) or CO(2) at 248 nm. Two intense transient features with origins near 1152 and 994 cm(-1) are assigned to syn-CH(3)OSO; the former is attributed to over...
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C6H5SO2 radicals were produced upon irradiation of three flowing mixtures: C6H5SO2Cl in N2, C6H5Cl and SO2 in CO2, and C6H5Br and SO2 in CO2, with a KrF excimer laser at 248 nm. A step-scan Fourier-transform spectrometer coupled with a multipass absorption cell was employed to record the time-resolved infrared (IR) absorption spectra of reaction intermediates. Two transient bands with origins a...
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ژورنال
عنوان ژورنال: Chemical Physics Letters
سال: 2006
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2005.12.029